| 2,390 | 69 | 94 |
| 下载次数 | 被引频次 | 阅读次数 |
随着社会经济的快速发展,水环境污染问题日益严重,水体重金属污染问题尤为突出。目前,重金属污水的处理方法主要有化学沉淀法、氧化还原法、离子交换法、电化学法、膜分离法和吸附法等,它们各自有其优缺点。吸附法在水体重金属污染治理领域有其特殊的优势,如操作简单、材料来源广泛和适用范围广等,其中,吸附材料是影响吸附法处理水体重金属污染的关键因素。综述了各种吸附材料在处理重金属污水方面的研究进展,在此基础上,对吸附法处理重金属污水的应用前景进行了展望。
Abstract：With the rapid development of social economy, the problem of water pollution is becoming more and more serious. At present, the treatment methods of heavy metal sewage mainly include chemical precipitation, oxidation and reduction, ion exchange, electrochemistry, membrane separation, adsorption and so on. Each of these methods has its own advantages and disadvantages. Adsorption method has its special advantages in the field of water treatment of heavy metal pollution, due to its simple operation, wide sources of materials and wide range of application. Adsorption materials are the key factor affecting the treatment of heavy metal pollution in water by adsorption. Research progresses of adsorption materials for heavy metal wastewater treatment were reviewed, and the prospect of future development was discussed. This paper reviewed the research progress of various adsorption materials in the treatment of heavy metal pollution in water, and made a prospect on the application of adsorption method in the treatment of heavy metal polluted water.
[1] SANTHOSH C,VELMURUGAN V,JACOB G,et al.Role of nanomaterials in water treatment applications:a review[J].Chemical engineering journal,2016,306:1116-1137.
[2] SRIVASTAVA N,MAJUMDER C.Novel biofiltration methods for the treatment of heavy metals from industrial wastewater[J].Journal of hazardous materials,2008,151(1):1-8.
[3] LAKATOS J,BROWN S,SNAPE C.Coals as sorbents for the removal and reduction of hexavalent chromium from aqueous waste streams[J].Fuel,2002,81(5):691-698.
[4] AHMED M,AHMARUZZAMAN M.A review on potential usage of industrial waste materials for binding heavy metal ions from aqueous solutions[J].Journal of water process engineering,2016,10:39-47.
[5] DHALLUIN M,RULL-BARRULL J,BRETEL G,et al.Chemically modified cellulose filter paper for heavy metal remediation in water[J].Acs sustainable chemistry,2017,5(2):1965-1973.
[6] PENG W,LI H,LIU Y,et al.A review on heavy metal ions adsorption from water by graphene oxide and its composites[J].Journal of molecular liquids,2017,230:496-504.
[7] DIAS J,ALVIM-FERRAZ M,ALMEIDA F,et al.Waste materials for activated carbon preparation and its use in aqueous-phase treatment:a review[J].Journal of environmental management,2007,85(4):833-846.
[8] BABEL S,KURNIAWAN T.Cr(VI) removal from synthetic wastewater using coconut shell charcoal and commercial activated carbon modified with oxidizing agents and/or chitosan[J].Chemosphere,2004,54(7):951-967.
[9] LI J,XING X,LI J,et al.Preparation of thiol-functionalized activated carbon from sewage sludge with coal blending for heavy metal removal from contaminated water[J].Environmental pollution,2017,234:677-683.
[10] BOHLI T,OUEDERNI A,FIOL N,et al.Single and binary adsorption of some heavy metal ions from aqueous solutions by activated carbon derived from olive stones[J].Desalination & water treatment,2015,53(4):1-7.
[11] PAP S,RADONIC J,TRIFUNOVIC S,et al.Evaluation of the adsorption potential of eco-friendly activated carbon prepared from cherry kernels for the removal of Pb2+,Cd2+ and Ni2+ from aqueous wastes[J].Journal of environmental management,2016,184:297-306.
[12] KASANIN-GRUBIN M.Clay mineralogy as a crucial factor in badland hillslope processes[J].Catena,2013,106(3):54-67.
[13] SPIERS G,DUDAS M,MUEHLENBACHS K,et al.Mineralogy and oxygen isotope geochemistry of clays from surficial deposits in the Athabasca Tar Sands area[J].Canadian journal of earth sciences,1984,21(1):53-60.
[14] SENGCO M,HAGSTROM J A,GRANELI E,et al.Removal of Prymnesium parvum (Haptophyceae) and its toxins using clay minerals[J].Harmful algae,2005,4(2):261-274.
[15] NGEONTAE W,AEUNGMAITREPIROM W,TUNTULANI T.Chemically modified silica gel with aminothioamidoanthraquinone for solid phase extraction and preconcentration of Pb(II),Cu(II),Ni(II),Co(II) and Cd(II)[J].Talanta,2007,71(3):1075-1082.
[16] CHOI J M,JEONG D,CHO E,et al.Chemically functionalized silica gel with alkynyl terminated monolayers as an efficient new material for removal of mercury ions from water[J].Journal of industrial & engineering chemistry,2016,35:376-382.
[17] SUHA S,GUPTA V K,CARROTT P,et al.Cellulose:a review as natural,modified and activated carbon adsorbent[J].Bioresour technol,2016,216:1066-1076.
[18] WU Z,CHENG Z,MA W.Adsorption of Pb(II) from glucose solution on thiol-functionalized cellulosic biomass[J].Bioresource technology,2012,104:807-809.
[19] CRINI G,BADOT P M.Application of chitosan,a natural aminopolysaccharide,for dye removal from aqueous solutions by adsorption processes using batch studies:a review of recent literature[J].Progress in polymer science,2008,33(4):399-447.
[20] KURITA K,KOJIMA T,NISHIYAMAY,et al.Synthesis and some properties of nonnatural Amino Polysaccharides:branched Chitin and chitosan[J].Macromolecules,2000,33(13):4711-4716.
[21] 蒋挺大.壳聚糖[M].北京:化学工业出版社,2007.
[22] LI N,BAI R.Development of chitosan-based granular adsorbents for enhanced and selective adsorption performance in heavy metal removal[J].Water science & technology:a journal of the international association on water pollution research,2006,54(10):103-113.
[23] KONDO K,MATSUMOTO M,OKAMOTO K.Enhanced adsorption of copper(II) ion on novel amidoxime chitosan resin[J].Journal of chemical engineering of Japan,1999,32(2):217-222.
[24] DAI J,YANG H,YAN H,et al.Phosphate adsorption from aqueous solutions by disused adsorbents:chitosan hydrogel beads after the removal of copper(II)[J].Chemical engineering journal,2011,166(3):970-977.
[25] KAMINSKI W,MODRZEJEWSKA Z.Application of chitosan membranes in separation of heavy metal ions[J].Separation science and technology,1997,32(16):2659-2668.
[26] JIANG W,HAIJIA S U,TAN T.Adsorption properties for heavy metal ions of molecular imprinting chitosan-coated diatomite beads in water-extraction liquid of Rhodiola L[J].Journal of chemical industry & engineering,2008,59(5):1179-1183.
[27] BASSI R,PRASHER S O,SIMPSON B K.Removal of selected metal ions from aqueous solutions using chitosan flakes[J].Separation science and technology,2000,35(4):547-560.
[28] CAO L,XU S,FENG S,et al.Adsorption of Zn (II) ion onto Crosslinked Amphoteric Starch in Aqueous Solutions[J].Journal of polymer research,2004,11(2):105-108.
[29] 徐琼,邹丽霞,欧阳明,等.交联两性淀粉的制备及其吸附Cr(Ⅵ)的性能研究[J].食品科技,2009(12):271-274.
[30] YANG Y T,WEI X Z,WAN J M,et al.Equilibrium and kinetic characteristic of adsorption of Cu2+,Pb2+ on a Novel Anionic Starch Microspheres[J].Water,air & soil pollution,2011,219(1):103-112.
[31] XU Y D,Yan X Y.Adsorption of Cr(VI) onto the cross-linked cationic starch and the establishment of the adsorption isotherm and kinetic equation[J].Advanced materials research,2012,518/519/520/521/522/523:285-288.
[32] GUCLU G,AI E,EMIK S,et al.Removal of Cu2+ and Pb2+ ions from aqueous solutions by starch-graft-acrylic acid/montmorillonite superabsorbent nanocomposite hydrogels[J].Polymer bulletin,2010,65(4):333-346.
[33] HAN H,CHEN X,JIN M.Synthesis of cross-linking cationic starch and adsorption of heavy metal ions[J].Environmental protection of chemical industry,2005,25(3):235-238.
[34] CELIK A,DEMIRBAS A.Removal of heavy metal ions from aqueous solutions via adsorption onto modified lignin from pulping wastes[J].Energy sources,2005,27(12):1167-1177.
[35] 任孟杰,夏强,周妍,等.改性木质素吸附重金属离子的研究与应用进展[J].化学工业与工程技术,2013,34(6):54-58.
[36] YANG L,YAN H Z.Modification of reed alkali lignin to adsorption of heavy metals[J].Advanced materials research,2013,622/623:1646-1650.
[37] PARAJULI D,INOUE K,OHTO K,et al.Adsorption of heavy metals on crosslinked lignocatechol:a modified lignin gel[J].Reactive & functional polymers,2005,62(2):129-139.
[38] GUO X,ZHANG S,SHAN X Q.Adsorption of metal ions on lignin[J].Journal of hazardous materials,2008,151(1):134-142.
[39] VOLESKY B.Biosorption and me[J].Water research,2007,41(18):4017-4029.
[40] ARIVALAGAN P,SINGARAJ D,HARIDASS V,et al.Removal of cadmium from aqueous solution by batch studies using Bacillus cereus[J].Ecological engineering,2014,71:728-735.
[41] BACHATE S P,NANDRE V S,GHATPANDE N S,et al.Simultaneous reduction of Cr(VI) and oxidation of As(III) by Bacillus firmus TE7 isolated from tannery effluent[J].Chemosphere,2013,90(8):2273-2278.
[42] KARIIMPOUR M,ASHRAFI S D,TAGHAVI K,et al.Adsorption of cadmium and lead onto live and dead cell mass of Pseudomonas aeruginosa:a dataset[J].Data in brief,2018,18:1185-1192.
[43] SARANYA K,SUNDARAMANICKAM A,SHEKHAR S,et al.Biosorption of multi-heavy metals by coral associated phosphate solubilising bacteria Cronobacter muytjensii KSCAS2[J].Journal of environmental management,2018,222:396-401.
[44] 王亚雄,郭瑾珑,刘瑞霞.微生物吸附剂对重金属的吸附特性[J].环境科学,2001,22(6):72-75.
[45] ABEDEL-ATY A M,AMMAR N S,ABDEL G,et al.Biosorption of cadmium and lead from aqueous solution by fresh water alga Anabaena sphaerica biomass[J].Journal of advanced research,2013,4(4):367-374.
[46] MOGHADDAM M R,FATEMI S,KESHTKAR A.Adsorption of lead (Pb2+) and uranium (UO) cations by brown algae:experimental and thermodynamic modeling[J].Chemical engineering journal,2013,231(9):294-303.
[47] WANG S,BOYJOO Y,CHOUEIB A,et al.Removal of dyes from aqueous solution using fly ash and red mud[J].Water research,2005,39(1):129-138.
[48] DIMITROVA S V.Metal sorption on blast-furnace slag[J].Water research,1996,30(1):228-232.
[49] NEHRENHEIM E,GUSTAFSSON J.Kinetic sorption modelling of Cu,Ni,Zn,Pb and Cr ions to pine bark and blast furnace slag by using batch experiments[J].Bioresource technology,2008,99(6):1571-1577.
[50] 简向阳,冯承娜,甘美娜,等.华南几种草本植物的水质净化能力研究[J].华北水利水电大学学报(自然科学版),2018,39(4):61-66.
基本信息:
DOI：10.19760/j.ncwu.zk.2019021
中图分类号:X52
引用信息:
[1]牛耀岚,吴曼菲,胡湛波.吸附法处理水体重金属污染的研究进展[J].华北水利水电大学学报(自然科学版),2019,40(02):46-51.DOI:10.19760/j.ncwu.zk.2019021.
基金信息:
广西科技基地和人才专项项目(桂科AD17195092);; 广西壮族自治区中青年教师基础能力提升项目(2018KY0663)