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2026, 02, v.47 103-110
纳米SiO2和混杂纤维增强环氧树脂水泥基修复材料抗压强度研究
基金项目(Foundation): 国家自然科学基金项目(52278283); 河南省杰出青年科学基金项目(212300410018)
邮箱(Email): zhangpeng@zzu.edu.cn;
DOI: 10.19760/j.ncwu.zk.2026028
发布时间: 2024-12-31
出版时间: 2024-12-31
网络发布时间: 2024-12-31
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摘要:

【目的】研究纳米SiO2和混杂纤维增强环氧树脂水泥基修复材料(NF-ECRM)抗压强度的变化规律,揭示环氧树脂乳液、纳米SiO2和聚乙烯醇(PVA)-钢混杂纤维对抗压强度的影响机理。【方法】通过立方体抗压强度试验分析了环氧树脂、纳米SiO2和PVA-钢混杂纤维的掺量对NF-ECRM抗压强度的影响规律;通过扫描电子显微镜试验研究,揭示NF-ECRM抗压强度的增强机理。【结果】随着环氧树脂掺量的增加,环氧树脂水泥基修复材料和NF-ECRM的抗压强度均呈下降趋势;NF-ECRM的抗压强度随着纳米SiO2掺量的增加呈逐渐上升的趋势,随着PVA纤维掺量的增加呈先增大后减小的趋势,且在PVA纤维掺量增加至0.9%时达到峰值。【结论】环氧树脂可有效缓解水泥基修复材料基体内应力,抑制微裂纹的产生和扩展;纳米SiO2可减少水泥基修复材料基体孔洞缺陷,提高界面过渡区的致密性;PVA-钢混杂纤维可显著提高水泥基修复材料基体的整体性和抗裂性。

Abstract:

【Objective】 This study aims to investigate the variation in compressive strength of nano-SiO2 and hybrid fiber-reinforced epoxy resin cementitious repair materials(NF-ECRM), and to reveal the influence mechanism of epoxy resin emulsion, nano-SiO2 and polyvinyl alcohol(PVA)-steel hybrid fiber on the compressive strength. 【Methods】 Cube compressive strength tests were conducted to analyze the effects of the contents of epoxy resin, nano-SiO2, and PVA-steel hybrid fibers on the compressive strength of NF-ECRM. Scanning electron microscope tests were performed to reveal the strengthening mechanism of the compressive strength of NF-ECRM. 【Results】 With the increase in epoxy resin content, the compressive strength of epoxy resin cementitious repair materials(ECRM) and NF-ECRM both showed a decreasing trend. Meanwhile, the compressive strength of NF-ECRM gradually increased with the increase in nano-SiO2 content, while it first increased and then decreased with the increase in PVA fiber content, reaching the peak when the PVA fiber content was 0.9%. 【Conclusion】 Epoxy resin can effectively relieve internal stress in the cementitious repair material matrix and inhibit the formation and expansion of micro-cracks. Nano-SiO2 can reduce pore defects of the cementitious repair material matrix and improve the compactness of the interfacial transition zone. Moreover, PVA-steel hybrid fiber can significantly enhance the integrity and crack resistance of the cementitious repair material matrix.

参考文献

[1] 田耀刚,鲁涛,赵成,等.水性环氧树脂-聚丙烯纤维改性水泥基快速修补砂浆性能研究[J].功能材料,2024,55(1):1031-1037.[TIAN Y G,LU T,ZHAO C,et al.Properties of rapid repair mortar modified with waterborne epoxy resin and polypropylene fiber[J].Journal of Functional Materials,2024,55(1):1031-1037.]

[2] 黄燕,许瑶怡,范萌萌,等.环氧树脂基混凝土裂缝快速修复材料的制备及性能研究[J].西部交通科技,2024(4):54-57.[HUANG Y,XU Y Y,FAN M M,et al.Preparation and properties of epoxy resin-based rapid repair materials for concrete cracks[J].Western China Communications Science & Technology,2024(4):54-57.]

[3] 王海明.水泥基环氧树脂灌浆材料的制备及性能研究[J].功能材料,2023,54(11):11015 -11021.[WANG H M.Preparation and properties of cement-based epoxy resin grouting materials[J].Journal of Functional Materials,2023,54(11):11015-11021.]

[4] 李刊,魏智强,乔宏霞,等.纳米SiO2改性聚合物水泥基材料性能试验研究[J].湖南大学学报(自然科学版),2021,48(11):150-159.[LI K,WEI Z Q,QIAO H X,et al.Experimental study on the properties of nano-SiO2 modified polymer cement-based materials[J].Journal of Hunan University (Natural Sciences),2021,48(11):150-159.]

[5] 肖其远,朱英英,杨奕,等.纳米SiO2对不同条件下聚合物改性砂浆强度的影响[J].混凝土,2022(2):136-139.[XIAO Q Y,ZHU Y Y,YANG Y,et al.Influence of nano-SiO2 on the strength of polymer-modified mortar under different conditions[J].Concrete,2022(2):136-139.]

[6] 丁伟正.耐碱玻璃纤维-环氧树脂增强水泥基透水混凝土性能研究[D].赣州:江西理工大学,2024.[DING W Z.Study on the properties of alkali-resistant glass fiber-epoxy resin reinforced cement-Based pervious concrete[D].Ganzhou:Jiangxi University of Science and Technology,2024.]

[7] 赵亮平,汤寄予,陈刚,等.高温中纤维纳米混凝土劈拉性能试验研究[J].华北水利水电大学学报(自然科学版),2023,44(5):94-100,108.[ZHAO L P,TANG J Y,CHEN G,et al.Experimental study on splitting tensile properties of fiber nano-concrete at high temperatures[J].Journal of North China University of Water Resources and Electric Power (Natural Science Edition),2023,44(5):94-100,108.]

[8] 卜静武,吴新宇,徐慧颖.纤维增强高性能混凝土常规三轴抗压破坏准则[J].华北水利水电大学学报(自然科学版),2023,44(1):71-78.[BU J W,WU X Y,XU H Y.Failure criterion of fiber-reinforced high-performance concrete under conventional triaxial compression[J].Journal of North China University of Water Resources and Electric Power (Natural Science Edition),2023,44(1):71-78.]

[9] 谈峰玲,吕淼,周浩,等.钢纤维增强聚合物水泥砂浆性能研究[J].混凝土与水泥制品,2024(6):68-71.[TAN F L,LV M,ZHOU H,et al.Study on properties of steel fiber reinforced polymer cement mortar[J].China Concrete and Cement Products,2024(6):68-71.]

[10] 陈卓异,寇子豪,熊永明,等.定向钢纤维水泥基复合材料的含砂率及定向时程影响规律[J].硅酸盐通报,2024,43(7):2346-2354.[CHEN Q Y,KOU Z H,XIONG Y M,et al.Influence of sand content and orientation time on the properties of aligned steel fiber cement-based composites[J].Bulletin of the Chinese Ceramic Society,2024,43(7):2346-2354.]

[11] 丁彦江.钢-PVA混杂纤维增强水泥基复合材料冲击压缩动力性能试验研究[D].广州:华南理工大学,2014.[DING Y J.Experimental study on impact compression dynamic properties of steel-PVA hybrid fiber reinforced cement-based composites[D].Guangzhou:South China University of Technology,2014.]

[12] 王玲玲,钟炀,李畅,等.PVA纤维和纳米SiO2对水泥基复合材料性能影响研究[J].混凝土,2023(12):115-119.[WANG L L,ZHONG Y,LI C,et al.Influence of PVA fiber and nano-SiO2 on the properties of cement-based composites[J].Concrete,2023(12):115-119.]

[13] 国家能源局.聚合物改性水泥砂浆试验规程:DL/T 5126—2021[S].北京:中国电力出版社,2021.[National Energy Administration.Test code for polymer modified cement mortar:DL/T 5126—2021[S].Beijing:China Electric Power Press,2021.]

[14] 梁学杰.环氧树脂改性水泥混凝土的制备及耐久性实验分析[J].功能材料,2023,54(3):7.[LIANG X J.Preparation and durability experimental analysis of epoxy resin modified cement concrete[J].Journal of Functional Materials,2023,54(3):7.]

[15] 李聪.聚氨酯/环氧树脂-水泥复合修补材料性能研究[D].哈尔滨:哈尔滨工业大学,2023.[LI C.Study on properties of polyurethane/epoxy resin-cement composite repair materials[D].Harbin:Harbin Institute of Technology,2023.]

[16] 中华人民共和国建设部.建筑砂浆基本性能试验方法标准:JGJ/T 70—2009[S].北京:中国建筑工业出版社,2009.[Ministry of Construction of the People′s Republic of China.Standard for test method of basic properties of construction mortar:JGJ/T 70—2009[S].Beijing:China Architecture & Building Press,2009.]

[17] 陈宗瑞.环氧树脂改性水泥修补砂浆的性能研究[D].武汉:武汉理工大学,2019.[CHEN Z R.Study on properties of epoxy resin modified cement repair mortar[D].Wuhan:Wuhan University of Technology,2019.]

[18] 黄展魏,陈伟,李秋,等.水性环氧树脂改性水泥砂浆力学性能及微观结构[J].硅酸盐通报,2017,36(8):2530-2535,2540.[HUANG Z W,CHEN W,LI Q,et al.Mechanical properties and microstructure of waterborne epoxy resin modified cement mortar[J].Bulletin of the Chinese Ceramic Society,2017,36(8):2530-2535,2540.]

[19] 吴剑扬,王长柏,吴捷豪,等.水性环氧树脂改性水泥灌浆料微观与力学性能研究[J].黑龙江工业学院学报(综合版),2023,23(11):125-132.[WU J Y,WANG C B,WU J H,et al.Study on microstructure and mechanical properties of waterborne epoxy resin modified cement grouting material[J].Journal of Heilongjiang University of Technology (Comprehensive Edition),2023,23(11):125-132.]

[20] 杨潮军.纳米改性聚合物水泥基材料的性能和修复试验研究[D].杭州:浙江大学,2016.[YANG C J.Experimental study on performance and repair of nano-modified polymer cement-based materials[D].Hangzhou:Zhejiang University,2016.]

[21] 王丹,张丽娜,侯鹏坤,等.纳米SiO2在水泥基材料中的应用研究进展[J].硅酸盐通报,2020,39(4):1003-1015.[WANG D,ZHANG L N,HOU P K,et al.Research progress on the application of nano-SiO2 in cement-based materials[J].Bulletin of the Chinese Ceramic Society,2020,39(4):1003-1015.]

[22] LING Y F,ZHANG P,WANG J,et al.Effect of PVA fiber on mechanical properties of cementitious composite with and without nano-SiO2[J].Construction and Building Materials,2019,229:117068.

[23] 何稳.钢纤维在超高性能混凝土中增强增韧作用的研究[D].长沙:湖南大学,2015.[HE W.Study on the strengthening and toughening effect of steel fiber in ultra-high performance concrete[D].Changsha:Hunan University,2015.]

[24] 苟鸿翔,朱洪波,周海云,等.定向分布钢纤维对超高性能混凝土的增强作用[J].硅酸盐学报,2020,48(11):1756-1764.[GOU H X,ZHU H B,ZHOU H Y,et al.Strengthening effect of aligned steel fiber on ultra-high performance concrete[J].Journal of the Chinese Ceramic Society,2020,48(11):1756-1764.]

基本信息:

DOI:10.19760/j.ncwu.zk.2026028

中图分类号:TV431.3

引用信息:

[1]吴靖江,张鹏,尉晓雪,等.纳米SiO_2和混杂纤维增强环氧树脂水泥基修复材料抗压强度研究[J].华北水利水电大学学报(自然科学版),2026,47(02):103-110.DOI:10.19760/j.ncwu.zk.2026028.

基金信息:

国家自然科学基金项目(52278283); 河南省杰出青年科学基金项目(212300410018)

发布时间:

2024-12-31

出版时间:

2024-12-31

网络发布时间:

2024-12-31

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